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PLASMA NITRIDING < APPLICATIONS < PLASMA NITRIDING FOR STAINLESS STEELS

A reliable solution for achieving surface hardening and low friction while preserving corrosion resistance.

Plasma Nitriding for Stainless Steels

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High-friction components with wear risk

Surface-hardening requirements in corrosive environments

Dimensional accuracy requirements without distortion

Porous or unsintered components with unsealed cavities

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Industrial Applications

ION HEAT’s plasma nitriding systems are suitable for stainless steel components operating under specific performance demands:

  • ION HEAT furnaces operate as hot-wall, vacuum-based systems with controlled hydrogen and nitrogen atmospheres. This oxygen-free environment prevents:

    • Decarburization

    • Chromium-carbide precipitation

    • Grain-boundary sensitization

  • Each process begins with an optimized argon sputtering stage. Argon’s relatively heavy atoms effectively reduce and clean the passive chromium-oxide layer, enabling nitrogen diffusion into the surface without forming chromium nitrides. The result is improved hardness and corrosion performance.

  • The process runs below the austenitizing range (~350–450 °C), preventing chromium-carbide formation and maintaining the stainless steel’s protective passive layer, which is essential for corrosion resistance.

  • Plasma nitriding occurs through nitrogen diffusion in the ferritic temperature range. Because no phase transformations take place, chromium remains stable in solid solution. Dimensional integrity is maintained, minimizing the need for post-process grinding.

  • Thanks to the vacuum environment and low process temperature, chromium at the surface remains available. Once the part is removed from the furnace and exposed to air, a new protective passive layer forms rapidly and naturally.

Process Advantages 

All stainless steels, especially austenitic grades, achieve a clean, uniform S-phase layer ready for demanding environments when treated with ION HEAT plasma nitriding systems.

Micrograph of plasma-nitrided AISI 304 stainless steel at 200× magnification showing uniform S-phase layer

Expanded Phase (S-Phase)

Plasma nitriding forms a dual-function surface: a hardened expanded-phase layer plus the material’s own chromium-oxide passive layer. One delivers high wear resistance, the other maintains corrosion protection.

Visual comparison table showing plasma nitriding vs hard chrome on a printed sheet mockup

Hard Chrome Replacement

Delivers a functionally equivalent surface in hardness, wear resistance, and friction performance, with no delamination or toxic residues. Most importantly, the process is fully repeatable and environmentally clean.

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Plasma nitriding provides metallurgical advantages that competing processes cannot match. For both commercial heat treaters and captive operations, two core properties define its superior performance.

Unmatched Properties

Choose the Right Furnace

Both GlowTech and NitrEos are engineered for plasma nitriding stainless steels with precision and repeatability.

For optimal results, they must be equipped with the ExtraGas feature, which includes dedicated argon and methane mass flow controllers.

GlowTech single-chamber plasma nitriding furnace manufactured by ION HEAT

Compare

Use the following resources to understand how plasma nitriding outperforms traditional stainless steel treatment methods.

Mockup of three consecutive pages, each displaying an infographic on stainless steel nitriding methods, comparing salt bath, gas, and plasma nitriding, highlighting surface hardness, corrosion resistance, and process characteristics.

Download PDF

Free eBook now available

“ABC Stainless Steels | Why plasma nitriding is the right way to treat them without damaging their anti-corrosion shield”, a clear, step-by-step guide explaining how the process works and why it outperforms traditional methods.

Cover of the eBook on plasma nitriding of stainless steels, shown on a tablet mockup
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